PUMA
Istituto dei materiali per l'elettronica ed il magnetismo     
Adhikary C., Sen R., Bocelli G., Cantoni A., Solzi M., Chaudhuri S., Koner S. Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystalstructure, and magnetic study. In: Journal of Coordination Chemistry, vol. 62 (22) pp. 3573 - 3582. Taylor & Francis, 2009.
 
 
Abstract
(English)
A new azido adduct of a tridentate Schiff-base copper(II) complex has been synthesized and characterized structurally and magnetically. X-ray single crystal structure analysis reveals that the asymmetric unit of [Cu2(L)2(1,1-N3)2][Cu(L)(N3)] (1) [HL = 1-(N-ortho-hydroxyacetophenimine)-2,2-diethyl-aminoethane] has two independent moieties. One of these forms a dimer, containing end-on azido bridges, with its center of inversion related equivalents. The complex crystallizes in monoclinic space group P21/c with a = 10.112(2), b = 31.938(4), c = 9.718(2) Aring and β = 95.00(2). Variable temperature magnetic susceptibility data show antiferromagnetic interactions between copper(II) centers.
URL: http://www.informaworld.com/smpp/content~db=all?content=10.1080/00958970903121289
DOI: 10.1080/00958970903121289
Subject Crystal structure
Tridentate Schiff-base ligand
Copper(II) azide complex
Antiferromagnetism


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